HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 878920Generated: November 1, 2026
Ethylene Glycol → 2-Hydroxyethyl ethyl(2-hydroxyethyl)phosphinate
https://huagongshe.com/reaction/878920
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Ethylene Glycol | HCID 174 | — |
| Reactant | Butyl ethyl(2-hydroxyethyl)phosphinate | HCID 46832566 | — |
| Catalyst | Potassium titanium oxalate | HCID 56841016 | — |
| Product | 2-Hydroxyethyl ethyl(2-hydroxyethyl)phosphinate | HCID 46832568 | 96% |
Reaction Steps
To 388 g (2 mol) of butyl ethyl(2-hydroxyethyl)phosphinate (produced as in Example 5) are added 155 g (2.5 mol) of ethylene glycol and 0.4 g of potassium titanyloxalate, followed by stirring at 200° C. for 2 h. Volatiles are distilled off by gradual evacuation to leave 315 g (96% of theory) of 2-hydroxyethyl ethyl-(2-hydroxyethyl)phosphinate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US08987490B2 |
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| Source dataset | uspto-grants-2015_03 |
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| ORD ID | ord-91c35ae2e5924dbca320f5182235abf7 |
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| Source note | uspto-grants-2015_03 |
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