化工社化工社 化学情報印刷レポート · 研究参考用
Pyridine → 8-Dodecen-1-ol, 1-acetate, (8Z)-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Pyridine | HCID 1049 | — |
| 反応物 | Acetic Anhydride | HCID 7918 | — |
| 反応物 | 8-Dodecen-1-ol, (8Z)- | HCID 5283295 | — |
| 反応物 | 11-Hexadecenal, (11Z)- | HCID 5364495 | — |
| 生成物 | 8-Dodecen-1-ol, 1-acetate, (8Z)- | HCID 5363377 | 90% |
反応手順
By acetylation of compound 2: According to the procedure for compound 6, Ac2O (0.29 mL, 3.0 mmol), pyridine (0.14 mL, 1.8 mmol), and alcohol 12 (0.28 g, 1.5 mmol) were reacted to provide 13 (19 g, 90% yield, 86% Z as determined by 1H-NMR) as a colorless oil.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08987531B2 |
| 出典データセット | uspto-grants-2015_03 |
| ORD ID | ord-8d0a89f683b240769b5490826310d381 |
| 出典メモ | uspto-grants-2015_03 |