化工社化工社 化学情報印刷レポート · 研究参考用
Oleyl Alcohol → (9z,12e)-Tetradecadien-1-ol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Oleyl Alcohol | HCID 5284499 | — |
| 反応物 | Myristoleyl alcohol | HCID 5364712 | — |
| 反応物 | trans-1,4-Hexadiene | HCID 5365552 | — |
| 溶媒 | Tetrahydrofuran | HCID 8028 | — |
| 生成物 | (9z,12e)-Tetradecadien-1-ol | HCID 5365760 | 68% |
反応手順
According to the procedure for compound 3, oleyl alcohol (1.0 g, 3.7 mmol) and 1,4-trans-hexadiene (4 mL) in THF (4 mL) were reacted with 1 (0.023 g, 1 mol %) to provide 15 0.53 g, 68% yield, 88% Z as determined by 1H-NMR) as a colorless oil; 1H NMR (CDCl3): δ 5.32-5.49 (4H, m), 3.64 (2H, br t, J=6.6 Hz), 2.71 (2H, m), 2.03 (2H, m), 1.03 (3H, m), 1.56 (2H, m), 1.25-1.39 (11H, m); 13C NMR (CDCl3): δ 130.4, 129.6, 127.7, 125.1, 63.1, 32.8, 30.4, 29.6, 29.5, 29.4, 29.2, 27.1, 25.7, 17.9; HRMS (FAB): 209.1906, [C14H26O−H]+ requires 209.1905.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08987531B2 |
| 出典データセット | uspto-grants-2015_03 |
| ORD ID | ord-63f63ff1568e47c2a2208435cb24b7a9 |
| 出典メモ | uspto-grants-2015_03 |