HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Hexene → 8Z-Tridecenyl acetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Hexene | HCID 11597 | — |
| Reactant | Non-8-enyl acetate | HCID 15673852 | — |
| Product | 8Z-Tridecenyl acetate | HCID 10014538 | — |
Reaction Steps
Reactions between 1-hexene and 8-nonenyl acetate were conducted using methods analogous to those described above using to form the pheromone derivative 17. When catalyzed by Ruthenium complex 1, the reaction proceeded in good yield (67%) with high Z-selectivity (91%) at a low catalyst loading (0.5 mol %).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08987531B2 |
| Source dataset | uspto-grants-2015_03 |
| ORD ID | ord-d311f3ee92db431b8a0eb371d8b2f2af |
| Source note | uspto-grants-2015_03 |