HuagongsheHuagongshe Chemistry Print Report · For research reference only
6-BroMo-1-Methyl-1H-benzo[d][1,2,3]triazole → 1-Methyl-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-benzotriazole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 6-BroMo-1-Methyl-1H-benzo[d][1,2,3]triazole | HCID 53393378 | — |
| Reactant | HCID 86700390 | HCID 86700390 | — |
| Product | 1-Methyl-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-benzotriazole | HCID 71757472 | — |
Reaction Steps
Prepared in a manner similar to 1-methyl-3-phenyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indazole, but using 6-bromo-1-methyl-1H-benzo[d][1,2,3]triazole instead of 5-bromo-1-methyl-3-phenyl-1H-indazole. 1H NMR (400 MHz, CDCl3) δ 8.04 (dd, J=6.8, 1.6 Hz, 2H), 7.79 (d, J=8.6 Hz, 1H), 4.33 (s, 3H), 1.39 (s, 12H).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08987250B2 |
| Source dataset | uspto-grants-2015_03 |
| ORD ID | ord-40dff001130640b89505e4bdf1a41225 |
| Source note | uspto-grants-2015_03 |