Phosphorus oxide (P4O10) → HCID 131729874, compound

HRID 883443Notes

Reaction equation

HRID 883443 reaction equation
[C:1]([O:6][CH2:7][CH:8]([CH2:10][O:11][C:12](=[O:16])[C:13]([CH3:15])=[CH2:14])[OH:9])(=[O:5])[C:2]([CH3:4])=[CH2:3].[O:17]=[P:18]12[O:29]P3(OP(OP(O3)([O:25]1)=O)(=O)[O:19]2)=O>>[C:1]([O:6][CH2:7][CH:8]([CH2:10][O:11][C:12](=[O:16])[C:13]([CH3:15])=[CH2:14])[OH:9])(=[O:5])[C:2]([CH3:4])=[CH2:3].[P:18]([O-:29])([O-:25])([O-:19])=[O:17]

Participants

3

Reactant 2

HCID 14812Phosphorus oxide (P4O10)HCID 745942-Hydroxy-1,3-propanediyl bismethacrylate

Product 1

HCID 131729874HCID 131729874, compound

Procedure

Reaction of 72 g glycerol-1,3-dimethacrylate with 17 g phosphorous pentoxide was performed under stirring, cooling with an ice bath and nitrogen atmosphere at room temperature for 48 hours to yield glycerol-1,3-dimethacrylate phosphate as a pale yellow liquid. The product was characterized by 1H- and 31P-NMR spectroscopy.

Workup

  1. temperaturecooling with an ice bath

Sources & evidence

ORD record
ord-5c4926da6d4e41a6a118014a0b9becb7
Source dataset
uspto-grants-2012_08
Patent number
US08236871B2

Reaction notes

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