HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzaldehyde → Stilbene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzaldehyde | HCID 240 | — |
| Reactant | Bromide ion | HCID 259 | — |
| Reactant | m-Chloroperbenzoic acid | HCID 70297 | — |
| Reactant | Phenyl formate | HCID 74626 | — |
| Product | Stilbene | HCID 11502 | — |
Reaction Steps
Formic acid phenyl ester 7 may be synthesized from the corresponding benzaldehyde via traditional oxidation methods known in the art. For example, Baeyer-Villiger oxidation using m-CPBA to form 7, followed by deformylation using a suitable base and exposure to bromide 8 affords stilbene analog 9.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08242144B2 |
| Source dataset | uspto-grants-2012_08 |
| ORD ID | ord-8069c601c35046bd880d04d0ef6b285e |
| Source note | uspto-grants-2012_08 |