HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrochloric Acid → Dimethylsilanediyl bis(trifluoromethanesulfonate)
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | Dichlorodimethylsilane | HCID 6398 | — |
| Reactant | Trifluoromethanesulfonic acid | HCID 62406 | — |
| Product | Dimethylsilanediyl bis(trifluoromethanesulfonate) | HCID 11121822 | 60.1% |
Reaction Steps
An oven-dried 100 mL-RB flask is charged with dichlorodimethylsilane (6.45 g, 0.05 mol). Then trifluoromethanesulfonic acid (15 g, 0.10 mol) is added dropwise. The mixture is heated at 60° C. until no HCl evolves. The residue is distilled to yield 10.7 g (60%) of the product as a clear liquid. 1H NMR (500 MHz, CDCl3, in ppm) δ 0.88 (s, 6H).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08247341B2 |
| Source dataset | uspto-grants-2012_08 |
| ORD ID | ord-a6d7098f37ab4a0a827bc4f1759d585c |
| Source note | uspto-grants-2012_08 |