Styrene → Butyl Acrylate

HRID 888705Notes

Reaction equation

HRID 888705 reaction equation
C=C[C:3]1[CH:8]=[CH:7][CH:6]=CC=1.[C:9]([O:13]CCC(O)=O)(=[O:12])[CH:10]=[CH2:11]>C(OC(OC(=O)C=C)CCCCCCCCCCC)(=O)C=C.C(S)CCCCCCCCCCC>[C:9]([O:13][CH2:6][CH2:7][CH2:8][CH3:3])(=[O:12])[CH:10]=[CH2:11]

Participants

5

Reactant 2

HCID 7501StyreneHCID 905582-Carboxyethyl acrylate

Product 1

HCID 8846Butyl AcrylateYield 686.3%

Reagents, catalysts & solvents 2

HCID 81951-DodecanethiolCatalystHCID 22448280Dodecanediol diacrylateCatalyst

Procedure

A mixture of about 1581 grams styrene, about 58 grams beta carboxyethyl acrylate (β-CEA), about 7 grams dodecanediol diacrylate (A-DOD), about 7.25 grams dodecanethiol and about 354 grams butyl acrylate was produced by dispersing under high shear conditions in a separate mixing vessel to form a homogenous emulsion.

Sources & evidence

ORD record
ord-7c3a3a720cfa40f389632958f6f25a18
Source dataset
uspto-grants-2012_08
Patent number
US08252493B2

Reaction notes

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