alpha-Bromo-2-nitrotoluene → HCID 59361539, compound

HRID 888804Notes

Reaction equation

HRID 888804 reaction equation
[CH:1]12[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[CH:2]1[N:11]1[C:14](=[O:15])[C:13]([CH3:17])([CH3:16])[NH:12]1)[CH2:8]2.[N+:18]([C:21]1[CH:28]=[CH:27][CH:26]=[CH:25][C:22]=1[CH2:23]Br)([O-:20])=[O:19]>>[CH3:16][C:13]1([CH3:17])[N:12]([CH2:23][C:22]2[CH:25]=[CH:26][CH:27]=[CH:28][C:21]=2[N+:18]([O-:20])=[O:19])[N:11]([CH:2]2[CH:3]3[CH2:4][CH:5]4[CH2:6][CH:7]([CH2:8][CH:1]2[CH2:10]4)[CH2:9]3)[C:14]1=[O:15]

Participants

3

Reactant 2

HCID 77569alpha-Bromo-2-nitrotolueneHCID 673028822-(Adamantan-2-yl)-4,4-dimethyl-1,2-diazetidin-3-one

Product 1

HCID 59361539HCID 59361539, compound

Procedure

2-(Adamantan-2-yl)-4,4-dimethyl-1,2-diazetidin-3-one and 2-nitrobenzyl bromide were used for a similar reaction and treatment as Process 6 of Example 1, and the title compound was obtained as a yellow oil.

Sources & evidence

ORD record
ord-e2163e379e224d1c8f57a759d8132c44
Source dataset
uspto-grants-2012_08
Patent number
US08252781B2

Reaction notes

Loading…