Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Hexane | HCID 8058 | — |
| Reactant | 4-dodecyloxycarbonyl-N-hydroxyphthalimide | HCID 10915765 | — |
| Catalyst | Manganous Acetate | HCID 12525 | — |
| Product | 3-Hexanone | HCID 11509 | — |
| Product | 2-Hexanone | HCID 11583 | — |
| Product | 3-Hexanol | HCID 12178 | — |
| Product | 2-Hexanol | HCID 12297 | — |
Reaction Steps
A mixture of 4 ml (31 mmol) of n-hexane, 0.03 mmol of 4-dodecyloxycarbonyl-N-hydroxyphthalimide, 0.0003 mmol of acetylacetonatocobalt(II) and 0.003 mmol of manganese(II) acetate was stirred at 100° C. in an atmosphere of air (10 atm=1 MPa) for 2 hours and thereby yielded 0.1 mmol of 2-hexanone, 0.09 mmol of 2-hexanol, 0.04 mmol of 3-hexanone and 0.05 mmol of 3-hexanol.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06998491B2 |
|---|
| Source dataset | uspto-grants-2006_02 |
|---|
| ORD ID | ord-592e9a4dc5134add85e98578538a8388 |
|---|
| Source note | uspto-grants-2006_02 |
|---|
