HuagongsheHuagongshe Chemistry Print Report · For research reference only
Allyl bromide → N,N-diallyl-4,4'-dinitro-2-biphenylamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Allyl bromide | HCID 7841 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | N-methyl-2-pyrrolidone | HCID 13387 | — |
| Reactant | 4,4'-Dinitro(1,1'-biphenyl)-2-amine | HCID 93265 | — |
| Product | N,N-diallyl-4,4'-dinitro-2-biphenylamine | HCID 22239440 | — |
Reaction Steps
A mixture of 4,4′-dinitro-2-biphenylamine (10.0 g), allyl bromide (20 mL), potassium carbonate (16 g) and NMP (100 mL) was heated to 90–95° C. for 90 hr. The mixture was extracted with tetrahydrofuran (THF)-ethyl acetate-water and purified by crystallization from ethyl acetate to give N,N-diallyl-4,4′-dinitro-2-biphenylamine (7.0 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07005165B2 |
| Source dataset | uspto-grants-2006_02 |
| ORD ID | ord-b81fa3ea0896455a9213f204d9adc483 |
| Source note | uspto-grants-2006_02 |