Chlorine → HCID 22241545, compound

HRID 892136Notes

Reaction equation

ClCl.[Cl:3][C:4]1[CH:30]=[C:29]([Cl:31])[CH:28]=[CH:27][C:5]=1[CH2:6][O:7][C:8]1[CH:9]=[C:10]([CH:24]=[CH:25][CH:26]=1)[O:11][CH2:12][C:13]1[CH:22]=[CH:21][CH:20]=[C:19]([CH3:23])[C:14]=1[C:15]([O:17]C)=[O:16]>>[Cl:3][C:4]1[CH:30]=[C:29]([Cl:31])[CH:28]=[CH:27][C:5]=1[CH2:6][O:7][C:8]1[CH:9]=[C:10]([CH:24]=[CH:25][CH:26]=1)[O:11][CH2:12][C:13]1[CH:22]=[CH:21][CH:20]=[C:19]([CH3:23])[C:14]=1[C:15]([OH:17])=[O:16]

Participants

Reactant 2

HCID 24526Chlorine

HCID 22241483HCID 22241483, compound

Product 1

HCID 22241545HCID 22241545, compound

Procedure

1H NMR (300 MHz, CDCl3) δ 7.40 (m, 2H), 7.34 (m, 2H), 7.24 (m, 2H), 7.17 (t, 1H), 6.59 (m, 3H), 5.19 (s, 2H), 5.03 (s, 2H), 2.45 (s, 3H). MS (ESI) 415 (M−H, Cl2 pattern). Prepared from methyl 2-[3-(2,4-dichloro-benzyloxy)-phenoxymethyl]-6-methyl-benzoate (example 6e).

Sources & evidence

ORD record: ord-7528ff09ed73416fb44668676a23909e
Source dataset: uspto-grants-2006_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07005440B1

Reaction notes

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