2-Amino-4-hydroxymethyl-6-methylbenzothiazole → 2-Amino-6-methylbenzothiazole-4-carboxaldehyde

HRID 892336Notes

Reaction equation

HRID 892336 reaction equation
[NH2:1][C:2]1[S:3][C:4]2[CH:10]=[C:9]([CH3:11])[CH:8]=[C:7]([CH2:12][OH:13])[C:5]=2[N:6]=1>[O-2].[Mn+4].[O-2]>[NH2:1][C:2]1[S:3][C:4]2[C:5](=[C:7]([CH:12]=[O:13])[CH:8]=[C:9]([CH3:11])[CH:10]=2)[N:6]=1

Participants

3

Reactant 1

HCID 198949572-Amino-4-hydroxymethyl-6-methylbenzothiazole

Product 1

HCID 198949682-Amino-6-methylbenzothiazole-4-carboxaldehyde

Reagents, catalysts & solvents 1

HCID 178418406HCID 178418406, compoundCatalyst

Procedure

67.6 g (0.348 mol) of 5b are treated with 241 g (2.77 mol) of manganese(IV) oxide in analogy to Example 1b.

Sources & evidence

ORD record
ord-0cd0ca4aa88243c390889bb7c74cb50c
Source dataset
uspto-grants-1992_06
Patent number
USRE033948

Reaction notes

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