Carbon Dioxide → HCID 19815635, compound

HRID 892393Notes

Reaction equation

HRID 892393 reaction equation
[C:1](=[O:3])=[O:2].[CH2:4]([S:12][CH2:13][CH2:14][NH2:15])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11]>C(#N)C>[C:1](=[O:3])([OH:2])[NH2:15].[CH2:4]([S:12][CH2:13][CH2:14][NH2:15])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11]

Participants

4

Reactant 2

HCID 280Carbon DioxideHCID 13628032HCID 13628032, compound

Product 1

HCID 19815635HCID 19815635, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

Carbon dioxide is bubbled through an acetonitrile (60 ml) solution of 10 g (52.8 mmoles) of 2-(octylthio)ethylamine to afford a white precipitate which is isolated by suction filtration. The product is washed three times with 10 ml portions of acetonitrile and is then washed three times with 20 mls portions of methyl t-butyl ether. The product is air dried to give 7.77 g of octylthioethylamine carbamic acid derivative as a white powder (yield, 62.1%). The product is further characterized by IR, proton NMR, and elemental analysis.

Workup

  1. customto afford a white precipitate which
  2. customis isolated by suction filtration
  3. washThe product is washed three times with 10 ml portions of acetonitrile
  4. washis then washed three times with 20 mls portions of methyl t-butyl ether
  5. customdried
  6. customto give

Sources & evidence

ORD record
ord-78d78381891a49ffabc868ba31ed90f2
Source dataset
uspto-grants-1992_06
Patent number
US05118534

Reaction notes

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