Methyl (E)-11-(2-chloroethylidene)-6,11-dihydrodibenz[b,e]oxepin-2-carboxylate → HCID 178497112, compound

HRID 892490Notes

Reaction equation

HRID 892490 reaction equation
Cl[CH2:2]/[CH:3]=[C:4]1/[C:5]2[CH:18]=[C:17]([C:19]([O:21][CH3:22])=[O:20])[CH:16]=[CH:15][C:6]=2[O:7][CH2:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][C:10]/1=2.[OH:23][C:24]1[NH:25][C:26]2[CH:32]=[CH:31][CH:30]=[CH:29][C:27]=2[N:28]=1>>[OH:23][C:24]1[N:28]([CH2:2]/[CH:3]=[C:4]2/[C:5]3[CH:18]=[C:17]([C:19]([O:21][CH3:22])=[O:20])[CH:16]=[CH:15][C:6]=3[O:7][CH2:8][C:9]3[CH:14]=[CH:13][CH:12]=[CH:11][C:10]/2=3)[C:27]2[CH:29]=[CH:30][CH:31]=[CH:32][C:26]=2[N:25]=1

Participants

3

Reactant 2

HCID 10448388Methyl (E)-11-(2-chloroethylidene)-6,11-dihydrodibenz[b,e]oxepin-2-carboxylateHCID 178517141HCID 178517141, compound

Product 1

HCID 178497112HCID 178497112, compound

Procedure

Compound h, 2.0 g and 4.3 g of 2-hydroxybenzimidazole were treated in a manner similar to Example 173 to give 0.3 g of the objective compound.

Sources & evidence

ORD record
ord-534cb607f215431385d8a7d70f112e74
Source dataset
uspto-grants-1992_06
Patent number
US05118701

Reaction notes

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