Ethanol → HCID 53944030, compound

HRID 892563Notes

Reaction equation

HRID 892563 reaction equation
[Cl:1][C:2]1[CH:3]=[CH:4][C:5]([CH:8]2[C:13]3[CH:14]=[C:15]([C:18]#[N:19])[CH:16]=[CH:17][C:12]=3[O:11][C:10]([CH3:21])([CH3:20])[CH2:9]2)=[N:6][CH:7]=1.C([OH:24])C>>[Cl:1][C:2]1[CH:3]=[CH:4][C:5]([CH:8]2[C:13]3[CH:14]=[C:15]([C:18]#[N:19])[CH:16]=[CH:17][C:12]=3[O:11][C:10]([CH3:21])([CH3:20])[CH2:9]2)=[N+:6]([O-:24])[CH:7]=1

Participants

3

Reactant 2

HCID 702EthanolHCID 19895643HCID 19895643, compound

Product 1

HCID 53944030HCID 53944030, compound

Procedure

In an analogous manner to that described in the first paragraph of Example 39, from 4-(5-chloro-2-pyridyl)-3,4-dihydro-2,2-dimethyl-2H-1-benzopyran-6-carbonitrile there was obtained 5-chloro-2-(6-cyano-3,4-dihydro-2,2-dimethyl-2H-1-benzopyran-4-yl)pyridine N-oxide of melting point 159°-161° C. (from ethanol).

Sources & evidence

ORD record
ord-f0c66b81faa549b68d0690c00f79390a
Source dataset
uspto-grants-1992_06
Patent number
US05118694

Reaction notes

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