Phosphoric Acid → Niobium phosphate

Niobic acid, Nb2O5 xH2O (60.33 g; 0.211 mole) is stirred in 85 percent phosphoric acid (602.20 g; 5.22 moles) at 150° C. The niobium oxide dissolves to form a pink solution, and upon further heating a precipitate forms. The precipitate is boiled in the phosphoric acid solution for about 2 hours with stirring. The mixture is cooled to room temperature, and the liquid is decanted from the precipitate. Water (500 ml) is added to the precipitate with stirring, and the precipitate is filtered. The washing and filtering cycle is repeated five times. The filtered solid is dried at 110° C. under air for 21/2 days to yield a niobium phosphate catalyst. The elemental analysis of the catalyst is consistent with the composition NbOPO4.

1. customto form a pink solution
2. temperatureupon further heating a precipitate forms
3. customthe liquid is decanted from the precipitate
4. additionWater (500 ml) is added to the precipitate
5. stirringwith stirring
6. filtrationthe precipitate is filtered
7. filtrationThe washing and filtering cycle
8. customThe filtered solid is dried at 110° C. under air for 21/2 days
9. customto yield a niobium phosphate catalyst

ORD record

ord-549f9da997c845bfb8d623ff4678e904

Source dataset

uspto-grants-1992_06

DOI

10.6084/m9.figshare.5104873.v1

Patent number

US05118850