HCID 67838128, compound → 2,2,3,6-Tetramethylcyclohex-3-ene-1-carbaldehyde

Participants

Reaction Steps

Prepared according to the method described, starting from 15.0 g (70 mmol) of PCC in 150 ml of CH2Cl2 and 8.38 g (50 mmol) of cis-2,2,3,6-tetramethyl-3-cyclohexene-1-methanol, obtained as in example 3b., in 50 ml of CH2Cl2. After stirring for 1 h, the reaction mixture was treated as described above to yield 6.77 g of the desired aldehyde in the form of a yellow oil (2 isomers, cis/trans~9:1).

Provenance & Evidence