HuagongsheHuagongshe Chemistry Print Report · For research reference only
Styrene → 1-Octene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Styrene | HCID 7501 | — |
| Reactant | Trifluoromethanesulfonyl chloride | HCID 79000 | — |
| Reactant | 1,1,2,2,3,3,4,4,5,5,6,6,6-Tridecafluorohexane-1-sulphonyl chloride | HCID 100374 | — |
| Product | 1-Octene | HCID 8125 | — |
| Product | 1-Hexene | HCID 11597 | — |
| Product | 1-Heptene | HCID 11610 | — |
Reaction Steps
Reactions were carried out generally in accordance with Example 1, except that trifluoromethanesulfonyl chloride was replaced by perfluorohexanesulfonyl chloride and styrene was replaced, respcetively, by 1-hexene (Example 15), 1-heptene (Example 16) and 1-octene (Example 17), whereby 1-butyl-1-chloro-2-perfluorohexylethane (Example 15), 1-heptyl-1-chloro-2-perfluorohexylethane (Example 16) and 1-hexyl-1-chloro-2-perfluorohexylethane (Example 17) were obtained, respectively, at a yield of 63%, 69% and 73%. The results of analyses of respective products are set forth below.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05118879 |
| Source dataset | uspto-grants-1992_06 |
| ORD ID | ord-1f97f4870f714f069b7a4546ba978e7f |
| Source note | uspto-grants-1992_06 |