Carbon Dioxide → HCID 54540029, compound

HRID 893041Notes

Reaction equation

HRID 893041 reaction equation
[CH2:1]=[CH:2][CH:3](O)[CH2:4][CH2:5][CH2:6][CH2:7][CH:8](O)[CH:9]=[CH2:10].[C:13](OC)(=O)[CH2:14][C:15]([CH3:17])=[O:16].[C:21](=O)=O.[CH3:24][OH:25]>>[CH3:17][C:15](=[O:16])[CH2:14][CH2:13][CH:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH:7]=[CH:8][CH2:9][CH2:10][C:24](=[O:25])[CH3:21]

Participants

5

Reactant 4

HCID 280Carbon DioxideHCID 887MethanolHCID 7757Methyl acetoacetateHCID 11745065HCID 11745065, compound

Product 1

HCID 54540029HCID 54540029, compound

Conditions

Temperature
200 °C

Procedure

A mixture of 36.4 g of a 91% strength (corresponding to 0.19 mole) of 1,9-decadiene-3,8-diol and 74.5 g (0.61 mole) of methyl acetoacetate was heated to 200° C. in the course of 3 h. At about 160° C., elimination of methanol began, followed by elimination of CO2. A total of 14.1 g of low boilers (bp.<70° C.) distilled off, and 9.5 l of CO2 (theory 10.2 l) were eliminated. The residue (73.5 g) was then subjected to fractional distillation under greatly reduced pressure (oil pump).

Workup

  1. customAt about 160° C.
  2. distillationA total of 14.1 g of low boilers (bp.<70° C.) distilled off
  3. distillationThe residue (73.5 g) was then subjected to fractional distillation under greatly reduced pressure (oil pump)

Sources & evidence

ORD record
ord-cd766527eab649d989e2cd37edf86e30
Source dataset
uspto-grants-1992_06
Patent number
US05120880

Reaction notes

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