Trifluoroiodomethane → HCID 86743769, compound

HRID 893257Notes

Reaction equation

I[As:2]([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[F:15][C:16]([F:19])([F:18])I>>[C:3]1([As:2]([C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[C:16]([F:19])([F:18])[F:15])[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

Participants

Reactant 2

HCID 16843Trifluoroiodomethane

HCID 238215Diphenylarsinous iodide

Product 1

HCID 86743769HCID 86743769, compound

Procedure

R. Cullen in an article "Perfluoroalkyl Arsenicals, Part II The Preparation and Properties of Aryl Perfluoroalkyl Arsenicals", reported in Canadian Journal of Chemistry, Volume 38, 1960, pg. 445-451, describes the reaction of iododiphenylarsine with trifluoroiodomethane to produce diphenyltrifluoromethylarsine. Thermal decomposition of diphenyltrifluoromethylarsine resulted in undisclosed black solid deposit.

Sources & evidence

ORD record: ord-9673e52b583a4cb3860e0a609d18591e
Source dataset: uspto-grants-1992_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05124278

Reaction notes

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