Pyridine → Heptadecyl acetate

HRID 893596Notes

Reaction equation

HRID 893596 reaction equation
[CH2:1]([C:15]1C=[C:17]([OH:21])[CH:18]=[CH:19][CH:20]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12]CC.[C:22](OC(=O)C)(=[O:24])[CH3:23].N1C=CC=CC=1>C(Cl)(Cl)Cl>[C:22]([O:21][CH2:17][CH2:18][CH2:19][CH2:20][CH2:15][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])(=[O:24])[CH3:23]

Participants

5

Reactant 3

HCID 1049PyridineHCID 7918Acetic AnhydrideHCID 144404953-Tetradecylphenol

Product 1

HCID 69967Heptadecyl acetate

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

A mixture of 18.85 g of 3-tetradecylphenol, 20 ml of acetic anhydride and 60 ml of pyridine was stirred for 16 hours, then diluted with chloroform, washed with aqueous sodium bicarbonate, dried and the solvent removed by evaporation with toluene, giving 21 g of the desired compound.

Workup

  1. washwashed with aqueous sodium bicarbonate
  2. customdried
  3. customthe solvent removed by evaporation with toluene

Sources & evidence

ORD record
ord-1c452a8387ea482c9df7b59e92678f6e
Source dataset
uspto-grants-1992_06
Patent number
US05126291

Reaction notes

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