tert-Butyl carbazate → HCID 178454365, compound

HRID 893915Notes

Reaction equation

HRID 893915 reaction equation
[C:1]([O:5][C:6]([CH3:9])([CH3:8])[CH3:7])(=[O:4])[NH:2][NH2:3].[Cl:10][C:11]([Cl:17])([Cl:16])[C:12](=[NH:15])OC>>[Cl:10][C:11]([Cl:17])([Cl:16])[C:12]([NH:3][NH:2][C:1]([O:5][C:6]([CH3:9])([CH3:8])[CH3:7])=[O:4])=[NH:15]

Participants

3

Reactant 2

HCID 70091tert-Butyl carbazateHCID 100479Methyl 2,2,2-trichloroacetimidate

Product 1

HCID 178454365HCID 178454365, compoundYield 86%

Procedure

A mixture of 2.9 g (0.025 mole) t-butyl carbazate and 10 ml (14.3 g, 0.08 mole) methyl 2,2,2-trichloroacetimidate was stirred 16 hours at room temperature. The solid that was left was washed with petroleum ether and dried to give 6.0 g (86% yield mp 150° C.). The structure was confirmed via infrared and elemental analysis.

Workup

  1. waitThe solid that was left
  2. washwas washed with petroleum ether
  3. customdried
  4. customto give 6.0 g (86% yield mp 150° C.)

Sources & evidence

ORD record
ord-77a8cfd3fead44c08f5cfaf120e78d49
Source dataset
uspto-grants-1981_08
Patent number
US04282169

Reaction notes

Loading…