HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzoyl Peroxide → 2-(Bromomethyl)benzo[b]thiophene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzoyl Peroxide | HCID 7187 | — |
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | 2-Methylbenzo(b)thiophene | HCID 70952 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | 2-(Bromomethyl)benzo[b]thiophene | HCID 13642605 | — |
Reaction Steps
A mixture of 4 g. (0.026 m.) of 2-methylbenzothiophene, 4.7 g. (0.027 m.) of N-bromosuccinimide, a catalytic amount of benzoyl peroxide and 250 ml. of carbon tetrachloride was stirred under irradiation for 30 minutes. The cooled and filtered mixture was evaporated to give an oily 2-bromomethylbenzothiophene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04282227 |
| Source dataset | uspto-grants-1981_08 |
| ORD ID | ord-b35554e709494b9b88225b2dc2398126 |
| Source note | uspto-grants-1981_08 |