Thioguaiacol → 4-methoxybenzenesulfenyl chloride

HRID 894037Notes

Reaction equation

[CH3:1][O:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1S.COC1C=C(S)C=CC=1.COC1C=CC=CC=1[S:27][Cl:28].COC1C=C(SCl)C=CC=1>>[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([S:27][Cl:28])=[CH:5][CH:4]=1

Participants

Reactant 4

HCID 23642Thioguaiacol

HCID 849893-Methoxybenzenethiol

HCID 12454886HCID 12454886, compound

HCID 14905666HCID 14905666, compound

Product 1

HCID 106073384-methoxybenzenesulfenyl chloride

Procedure

By the same procedure or by the procedure of Example 13, o-methoxythiophenol and m-methoxythiophenol are converted, respectively, to o-methoxybenzenesulfenyl chloride and m-methoxybenzenesulfenyl chloride.

Sources & evidence

ORD record: ord-18ba98d6ebd14103890fd4bda2497e50
Source dataset: uspto-grants-1981_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04282242

Reaction notes

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