HuagongsheHuagongshe Chemistry Print Report · For research reference only
Trifluoroacetic anhydride → 2-Bromo-6H-dibenz[b,e]oxepin-11-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Trifluoroacetic anhydride | HCID 9845 | — |
| Reactant | 2-(4-Bromophenoxymethyl)benzoic acid | HCID 10709836 | — |
| Product | 2-Bromo-6H-dibenz[b,e]oxepin-11-one | HCID 12929131 | — |
Reaction Steps
Reflux 120 gm. of o-(p-bromophenoxymethyl)benzoic acid in 500 cc. of trifluoroacetic anhydride containing 0.5 cc. of boron trifluoride-ether complex for 31/2 hours. Cool, separate the solids by filtration, and wash with ether in order to obtain the title product (m.p. 136°-139° C.).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04282365 |
| Source dataset | uspto-grants-1981_08 |
| ORD ID | ord-8f99849fe0cf4d9cbff1d35a73ed03e0 |
| Source note | uspto-grants-1981_08 |