HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Carbonate → N-ethyl-N-phenyl-o-(2,6-dichloroanilino)phenylacetamide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 2,6-Dichloroaniline | HCID 11846 | — |
| Reactant | N-ethyl-N-phenyl-(o-bromophenyl)acetamide | HCID 12884243 | — |
| Catalyst | Copper | HCID 23978 | — |
| Solvent | O-Xylene | HCID 7237 | — |
| Product | N-ethyl-N-phenyl-o-(2,6-dichloroanilino)phenylacetamide | HCID 12884244 | 77.4% |
Reaction Steps
A mixture of 6.36 g (0.02 mole) of N-ethyl-N-phenyl-(o-bromophenyl)acetamide having a boiling point of 185° to 190° C. under 2 mmHg, 6.48 g (0.04 mole) of 2,6-dichloroaniline, 3.0 g (0.02 mole) of anhydrous potassium carbonate, 2.0 g of copper powder and 2.0 g of cuprous bromide was reacted in 100 ml of xylene in the same manner as in Example 22 to obtain 6.1 g of a colorless prism having a melting point of 121° to 123° C. The yield was 77.4%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04283532 |
| Source dataset | uspto-grants-1981_08 |
| ORD ID | ord-880d727506954c17884fd4f70af46584 |
| Source note | uspto-grants-1981_08 |