2,4,6-Trimethylaniline → HCID 13881502, compound

HRID 894592Notes

Reaction equation

HRID 894592 reaction equation
[CH3:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([CH3:8])[C:3]=1[NH:9][CH2:10][CH:11]([NH:13][C:14]1[C:19]([CH3:20])=[CH:18][C:17]([CH3:21])=[CH:16][C:15]=1[CH3:22])[CH3:12].ClC(C)[CH2:25][NH:26]C1C(C)=CC=CC=1C.CC1C=C(C)C=C(C)C=1N>>[CH3:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([CH3:8])[C:3]=1[N:9]1[CH2:10][CH:11]([CH3:12])[N:13]([C:14]2[C:19]([CH3:20])=[CH:18][C:17]([CH3:21])=[CH:16][C:15]=2[CH3:22])[C:25]1=[NH:26]

Participants

4

Reactant 3

HCID 69132,4,6-TrimethylanilineHCID 13674776HCID 13674776, compoundHCID 20512469HCID 20512469, compound

Product 1

HCID 13881502HCID 13881502, compoundYield 87.6%

Procedure

1-(2',6'-Dimethylphenyl-amino)-2-(2',4',6'-trimethylphenyl-amino)-propane, applied as starting substance, is prepared by reacting N-(β-chloropropyl)-2,6-dimethyl-aniline, a compound prepared according to Example 3, Method (b), point (a), with 2,4,6-trimethylaniline under the conditions specified in Example 16, point (c). The aimed compound is obtained with a yield of 87.6%; m.p.: 128°-130° C. (dihydrochloride).

Workup

  1. customis prepared
  2. customa compound prepared

Sources & evidence

ORD record
ord-0124a5e5e61345aba0cfe05e1678f3c4
Source dataset
uspto-grants-1981_08
Patent number
US04284642

Reaction notes

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