HuagongsheHuagongshe Chemistry Print Report · For research reference only
Propionic Acid → Alphamethyl-gamma-n-hexyl-butyrolactone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Propionic Acid | HCID 1032 | — |
| Reactant | 1-Octene | HCID 8125 | — |
| Reactant | Potassium propionate | HCID 23663619 | — |
| Catalyst | Manganese(3+) | HCID 105130 | — |
| Product | Alphamethyl-gamma-n-hexyl-butyrolactone | HCID 12648626 | — |
Reaction Steps
Octene-1 in an amount of 2.24 g. and 11.65 g. of manganic acetate, Mn(C2H3O2)3. 2H2O, (comprising two equivalents of Mn+3 based on titration value), were refluxed under nitrogen in 200 ml. propionic acid containing 20 g. potassium propionate. In less than an hour a good yield of alphamethyl-gamma-n-hexyl-butyrolactone was obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04285868 |
| Source dataset | uspto-grants-1981_08 |
| ORD ID | ord-3b17b788f53a4aaebed07b8d9113abd1 |
| Source note | uspto-grants-1981_08 |