Cyclododecanone → 1-(Morpholino-propoxyimino)cyclododecane

HRID 894998Notes

Reaction equation

HRID 894998 reaction equation
[C:1]1(=O)[CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.Cl.Cl.[O:16]1[CH2:21][CH2:20][N:19]([CH2:22][CH2:23][CH2:24][O:25][NH2:26])[CH2:18][CH2:17]1.C(O)(=O)/C=C/C([O-])=O>>[O:16]1[CH2:17][CH2:18][N:19]([CH2:22][CH2:23][CH2:24][O:25][N:26]=[C:1]2[CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]2)[CH2:20][CH2:21]1

Participants

4

Reactant 3

HCID 13246CyclododecanoneHCID 6183479Fumarate(1-)HCID 21978813Morpholinopropoxyamine dihydrochloride

Product 1

HCID 132058081-(Morpholino-propoxyimino)cyclododecane

Procedure

Starting from 18.23 g. (0.1 moles) of cyclododecanone and 25.64 g. (0.11 moles) of morpholinopropoxyamine dihydrochloride the title compound is prepared as in Example 13. Yield: 28.4 g. (87%). Hydrogen fumarate, m.p.: 118°-120° C.

Sources & evidence

ORD record
ord-d5d8d935a6644b63bbb2c593dad522e7
Source dataset
uspto-grants-1981_08
Patent number
US04285942

Reaction notes

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