Hydrazine → HCID 136359185, compound

HRID 895001Notes

Reaction equation

HRID 895001 reaction equation
[CH3:1][C:2]12[CH2:12][CH2:11][CH:5]([C:6](=[N:9][OH:10])[C:7]1=O)[CH:4]([CH3:13])[O:3]2.[NH2:14][NH2:15]>C(O)C>[CH3:1][C:2]12[CH2:12][CH2:11][CH:5]([C:6](=[N:9][OH:10])[C:7]1=[N:14][NH2:15])[CH:4]([CH3:13])[O:3]2

Participants

4

Reactant 2

HCID 9321HydrazineHCID 86737965HCID 86737965, compound

Product 1

HCID 136359185HCID 136359185, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

A mixture of 1.83 g. (0.01 mole) 1,3-dimethyl-2-oxabicyclo[2,2,2]octan-5,6-dione-5-oxime and 0.35 ml. (0.011 mole) anhydrous hydrazine (98%) in 25 ml. absolute ethanol is refluxed under nitrogen at a bath temperature of 80° C. for 1 hour. Evaporation of the solvent gives 1,3-dimethyl-2-oxa-bicyclo[2,2,2]octan-5,6-dione-5-oxime-6-hydrazone.

Workup

  1. additionA mixture of 1.83 g
  2. customEvaporation of the solvent

Sources & evidence

ORD record
ord-777b7eee3d114927a507276c06dc3c71
Source dataset
uspto-grants-1981_08
Patent number
US04285944

Reaction notes

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