Anthragallol → 2-Anthracenesulfonic acid, 4-[[4-(acetylamino)phenyl]amino]-1-amino-9,10-dihydro-9,10-dioxo-

HRID 895030Notes

Reaction equation

HRID 895030 reaction equation
CC1C=CC(NC2C=CC(N[C:16]3[CH:21]=[CH:20][C:19](C)=[CH:18][C:17]=3[S:23]([O-:26])(=[O:25])=[O:24])=C3C(C4C(C(=O)C=23)=CC=CC=4)=O)=C([S:37]([O-:40])(=[O:39])=[O:38])C=1.[Na+:41].[Na+].C1C=C2[C:49](C3C(C(=O)C2=CC=1)=C(O)C(O)=C(O)C=3)=[O:50].C[C:63]1[C:68]([NH:69][C:70]2[CH:75]=[CH:74][C:73]([NH:76]C3C(C)=CC(C)=C(S([O-])(=O)=O)C=3C)=[C:72]3[C:90]([C:92]4[C:97]([C:98](=[O:99])[C:71]=23)=[CH:96][CH:95]=[CH:94][CH:93]=4)=[O:91])=[C:67](C)[C:66](S([O-])(=O)=O)=[C:65](C)[CH:64]=1.[Na+].[Na+].CC1C=CC=C(Cl)C=1[N:116]1N=C(C)[CH:119](N=NC2C=C(NC(C3C=CC4N=C(Cl)NN([O-])C=4C=3)=O)C=CC=2S(O)(=O)=O)[C:117]1=[O:118].[Na+].C[CH2:152][O:153][C:154]1[CH:159]=[CH:158][C:157]([N:160]=[N:161][C:162]2[C:171]3[C:166](=[CH:167]C=CC=3)[C:165]([N:172]=[N:173]C3C=CC=C(S([O-])(=O)=O)C=3)=[CH:164][CH:163]=2)=[CH:156][CH:155]=1.[Na+]>CC(/C(/C([O-])=NC1C=CC=CC=1)=N/NC1C=C(S(N)(=O)=O)C=CC=1[O-])=O.CC(/C(/C([O-])=NC1C=CC=CC=1)=N/NC1C=C(S(N)(=O)=O)C=CC=1[O-])=O.[Co+2]>[CH3:167][C:166]1[C:165]([N:172]=[N:173][C:20]2[CH:21]=[CH:16][C:17]([S:23]([O-:26])(=[O:24])=[O:25])=[CH:18][CH:19]=2)=[CH:164][C:163]([O:50][CH3:49])=[C:162]([N:161]=[N:160][C:157]2[CH:158]=[CH:159][C:154]([O:153][CH3:152])=[CH:155][CH:156]=2)[CH:171]=1.[Na+:41].[CH3:119][C:117]([NH:116][C:65]1[CH:66]=[CH:67][C:68]([NH:69][C:70]2[C:71]3[C:98]([C:97]4[C:92]([C:90](=[O:91])[C:72]=3[C:73]([NH2:76])=[C:74]([S:37]([OH:40])(=[O:38])=[O:39])[CH:75]=2)=[CH:93][CH:94]=[CH:95][CH:96]=4)=[O:99])=[CH:63][CH:64]=1)=[O:118]

Participants

8

Reactant 5

HCID 11768AnthragallolHCID 20431Benzenesulfonic acid, 2,2′-[(9,10-dihydro-9,10-dioxo-1,4-anthracenediyl)diimino]bis[5-methyl-, sodium salt (1:2)2×HCID 20551C.I. Acid Blue 80HCID 2367475612777-30-9HCID 23688093C.I. Acid Orange 127

Product 2

HCID 229362-Anthracenesulfonic acid, 4-[[4-(acetylamino)phenyl]amino]-1-amino-9,10-dihydro-9,10-dioxo-HCID 23703979C.I. Acid Orange 156

Reagents, catalysts & solvents 1

HCID 178468362HCID 178468362, compoundCatalyst

Procedure

Proceeding in a manner analogous to Example 5 but replacing for the ground dyeing the 12 parts of dyestuff C.I. Acid Green 106 by a mixture of 2.2 parts of dyestuff C.I. Acid Brown 298, 0.7 parts of dyestuff C.I. Acid Green 106 and 8.24 parts of dyestuff C.I. Acid Blue 80 (K'-value=9), and for the local printing the mixture of C.I. Acid Yellow 151, C.I. Acid Yellow 127 and C.I. Acid Orange 127 by a mixture of 2 parts of dyestuff C.I. Acid Orange 156 (K-value=2.5) and 0.4 parts of dyestuff C.I. Acid Blue 40 (K-value=2), similar good results are obtained.

Sources & evidence

ORD record
ord-f182839495724a1dadf45505eb79b596
Source dataset
uspto-grants-1981_08
Patent number
US04285691

Reaction notes

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