tert-Butyldimethylsilyl chloride → HCID 11270883, compound

Participants

Reaction Steps

The title compound was prepared by reacting 3,6-dibromo-8-chloro-2-naphthol (3.00 g, 8.92 mmol) with TBDMS-Cl (1.75 g, 150.7 mmol) according to method F to yield 3.36 g (84%) of a white solid: mp 58-64° C.; 1H NMR (CDCl3): δ 0.34 (6H, s), 1.08 (9H, s), 7.57 (1H, s), 7.62 (1H, d, J=1.72 Hz), 7.75 (1H, d, J=1.24 Hz), 7.97 (1H, s); MS (ESI) m/z333/335/337 (M−H)−.

Provenance & Evidence