HuagongsheHuagongshe Chemistry Print Report · For research reference only
(3S)-3-ethyl-7-fluoro-4-[(4-hydroxyphenyl)sulfonyl]-1-methyl-3,4-dihydroquinoxalin-2(1H)-one → (3S)-1,3-Diethyl-7-fluoro-4-[(4-hydroxyphenyl)sulfonyl]-3,4-dihydroquinoxalin-2(1 h)-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (3S)-3-ethyl-7-fluoro-4-[(4-hydroxyphenyl)sulfonyl]-1-methyl-3,4-dihydroquinoxalin-2(1H)-one | HCID 11639171 | — |
| Reactant | (3S)-1,3-diethyl-7-fluoro-4-[(4-methoxyphenyl)sulfonyl]-3,4-dihydroquinoxalin-2(1H)-one | HCID 69223084 | — |
| Product | (3S)-1,3-Diethyl-7-fluoro-4-[(4-hydroxyphenyl)sulfonyl]-3,4-dihydroquinoxalin-2(1 h)-one | HCID 11574408 | — |
Reaction Steps
(3S)-1,3-Diethyl-7-fluoro-4-[(4-methoxyphenyl)sulfonyl]-3,4-dihydroquinoxalin-2(1H)-one was treated according to the procedure for the preparation of (3S)-3-ethyl-7-fluoro-4-[(4-hydroxyphenyl)sulfonyl]-1-methyl-3,4-dihydroquinoxalin-2(1H)-one (see Example 29) to yield (3S)-1,3-Diethyl-7-fluoro-4-[(4-hydroxyphenyl)sulfonyl]-3,4-dihydroquinoxalin-2(1 h)-one. MS (ESI) m/z 379 ([M+H]+); MS (ESI) m/z 377 ([M−H]−).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07351709B2 |
| Source dataset | uspto-grants-2008_04 |
| ORD ID | ord-719a77d82fa84b52a8b403caa4a8d692 |
| Source note | uspto-grants-2008_04 |