Methyl 5-(chloromethyl)-2-furoate → HCID 11233065, compound

HRID 899523Notes

Reaction equation

HRID 899523 reaction equation
[OH:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[CH:13]=[CH:12][C:11]([N+:14]([O-:16])=[O:15])=[CH:10][CH:9]=2)=[CH:4][CH:3]=1.C[O:18][C:19]([C:21]1[O:22][C:23]([CH2:26]Cl)=[CH:24][CH:25]=1)=[O:20]>>[N+:14]([C:11]1[CH:12]=[CH:13][C:8]([C:5]2[CH:4]=[CH:3][C:2]([O:1][CH2:26][C:23]3[O:22][C:21]([C:19]([OH:20])=[O:18])=[CH:25][CH:24]=3)=[CH:7][CH:6]=2)=[CH:9][CH:10]=1)([O-:16])=[O:15]

Participants

3

Reactant 2

HCID 75065Methyl 5-(chloromethyl)-2-furoateHCID 1380784-Hydroxy-4'-nitrobiphenyl

Product 1

HCID 11233065HCID 11233065, compound

Procedure

5-(4′-Nitro-biphenyl-4-yloxymethyl)-furan-2-carboxylic acid was prepared using general procedure A from 4-hydroxy-4′-nitrobiphenyl (available from TCI America, Portland, Oreg.) and 5-chloromethylfuran-2-carboxylic acid methyl ester (available from Aldrich, Milwaukee, Wis., or from Maybridge plc, Tintagel, UK). Yield: 40 mg. Mass spectrum (ES) MH+=340.

Sources & evidence

ORD record
ord-4cc4df8334944382abcfb07e83037bc4
Source dataset
uspto-grants-2008_04
Patent number
US07355049B2

Reaction notes

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