HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethanol → HCID 10117272, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethanol | HCID 702 | — |
| Reactant | HCID 10117272 | HCID 10117272 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Product | HCID 10117272 | HCID 10117272 | — |
| Product | Isohexane ethyl acetate | HCID 21882781 | — |
| Product | HCID 87088216 | HCID 87088216 | — |
Reaction Steps
The product of step c) (189 mg) in dry ethanol (18 ml) was treated with a slurry of 10% Pd/C (20 mg) in dry ethanol (2 ml) and hydrogenated at 4 bar for 75 min. Filtration from catalyst and evaporation gave a residue which was purified by chromatography in two stages: firstly (SiO2/3:1 ethyl acetate-isohexane) and secondly (SiO2/2:1 isohexane-acetone) to afford the title compound (85 mg).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07361660B2 |
| Source dataset | uspto-grants-2008_04 |
| ORD ID | ord-be24e0b9b0964b9294eed4db58a2413c |
| Source note | uspto-grants-2008_04 |