HRID903025

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CC(C)(c1ccccc1)c1cc(N=Nc2ccccc2[N+](=O)[O-])c(O)c(C(C)(C)c2ccccc2)c1

HCID116810

2,4-Bis(1-methyl-1-phenylethyl)-6-((2-nitrophenyl)azo)phenol

C30H29N3O3

结构：CC(C)(c1ccccc1)c1cc(N=Nc2ccc(Cl)cc2[N+](=O)[O-])c(O)c(C(C)(C)c2ccccc2)c1

HCID135588812

未命名化合物

PRODUCTS

生成物

结构：CC(C)(c1ccccc1)c1cc(-n2nc3ccc(Cl)cc3n2)cc(C(C)(C)c2ccccc2O)c1

HCID86737246

未命名化合物

收率 70%

PROCEDURE

实验过程

When, using the general procedure of example 3, the amount of 4-chloro-2-nitro-2'-hydroxy-3',5'-di-(α,α-dimethylbenzyl)azobenzene was substituted for 2-nitro-2'-hydroxy-3',5'-di-(α,α-dimethylbenzyl)azobenzene, the above-named compound was prepared in a yield of 70.0% as light tan crystalls melting at 160°-161° C.

WORKUP

后处理

customthe above-named compound was prepared in a yield of 70.0% as light tan crystalls melting at 160°-161° C.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-9aa73575fdf54e74a8c551487f4284b1
来源数据集: uspto-grants-1980_10
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04226763
来源说明: uspto-grants-1980_10

反应 SMILES

[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([N:8]=[N:9][C:10]2[CH:15]=[C:14]([C:16]([CH3:24])([CH3:23])[C:17]3[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=3)[CH:13]=[C:12]([C:25]([CH3:33])([CH3:32])[C:26]3[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=3)[C:11]=2O)=[C:4]([N+:35]([O-])=O)[CH:3]=1.[N+](C1C=CC=CC=1N=NC1C=C(C(C)(C)C2C=CC=CC=2)C=C(C(C)(C)C2C=CC=CC=2)C=1O)([O-])=[O:39]>>[Cl:1][C:2]1[CH:7]=[CH:6][C:5]2=[N:8][N:9]([C:10]3[CH:11]=[C:12]([C:25]([CH3:33])([CH3:32])[C:26]4[CH:27]=[CH:28][CH:29]=[CH:30][C:31]=4[OH:39])[CH:13]=[C:14]([C:16]([CH3:23])([CH3:24])[C:17]4[CH:18]=[CH:19][CH:20]=[CH:21][CH:22]=4)[CH:15]=3)[N:35]=[C:4]2[CH:3]=1