HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dichloromethane → Trans-2,6,6-trimethyl-1-[1-hydroxy-2-butenyl]-1,2-epoxycyclohexane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dichloromethane | HCID 6344 | — |
| Reactant | Peracetic Acid | HCID 6585 | — |
| Reactant | Sodium Acetate | HCID 517045 | — |
| Reactant | 2,6,6-Trimethyl-1-[1-hydroxy-2-butenyl]-1-cyclohexene | HCID 53646445 | — |
| Solvent | Water | HCID 962 | — |
| Product | Trans-2,6,6-trimethyl-1-[1-hydroxy-2-butenyl]-1,2-epoxycyclohexane | HCID 23338018 | — |
Reaction Steps
21 g. of 40% peracetic acid and 0.6 g. of sodium acetate were added under nitrogen to a suspension of 2,6,6-trimethyl-1-[1-hydroxy-2-butenyl]-1-cyclohexene (19.4 g.) and 12 g. of sodium acetate in 35 ml. of CH2Cl2 at 20°. The reaction mixture was left 2 more hours with stirring and it was then poured into 250 ml. of water.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04226892 |
| Source dataset | uspto-grants-1980_10 |
| ORD ID | ord-c84ef4f9ac44445fb2b18c1dc9419921 |
| Source note | uspto-grants-1980_10 |