Hexamethylenetetramine → Molybdenum hexamethylenetetramine

HRID 903308Notes

Reaction equation

HRID 903308 reaction equation
[CH2:1]1[N:6]2[CH2:7][N:8]3[CH2:10][N:4]([CH2:5]2)[CH2:3][N:2]1[CH2:9]3.O[Mo:12](O)(=O)=O.[NH4+].[NH4+].[O-][Mo]([O-])(=O)=O>O>[Mo:12].[CH2:1]1[N:6]2[CH2:7][N:8]3[CH2:10][N:4]([CH2:5]2)[CH2:3][N:2]1[CH2:9]3

Participants

5

Reactant 3

HCID 4101HexamethylenetetramineHCID 61578Diammonium molybdateHCID 82208Molybdic acid

Product 1

HCID 131710930Molybdenum hexamethylenetetramine

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

Hexamethylenetetramine molybdate having a 2/1 molybdenum/hexamethylenetetramine molar ratio was prepared as follows. 10 grams of hexamethylenetetramine was dissolved in 100 ml water heated near reflux temperature. 24.01 grams of commercial, so-caled "molybdic acid" (actually at least one ammonium molybdate) was dissolved in 169 ml water heated to reflux temperature. The first solution was added to the second solution.

Workup

  1. temperatureheated
  2. temperaturenear reflux temperature
  3. temperatureheated
  4. temperatureto reflux temperature
  5. additionThe first solution was added to the second solution

Sources & evidence

ORD record
ord-810cfe5dcbfb4da5a7bcf4d951337977
Source dataset
uspto-grants-1980_10
Patent number
US04226987

Reaction notes

Loading…