HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanethiol → Ethyl 2-[(methylsulfanyl)methyl]prop-2-enoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanethiol | HCID 878 | — |
| Reactant | 2-(Bromomethyl)acrylic acid ethyl ester | HCID 310620 | — |
| Reactant | Sodium | HCID 5360545 | — |
| Solvent | Ethanol | HCID 702 | — |
| Solvent | Water | HCID 962 | — |
| Product | Ethyl 2-[(methylsulfanyl)methyl]prop-2-enoate | HCID 12463627 | — |
Reaction Steps
A solution of methylmercaptan (4.8 g.) and sodium (2.3 g.) in absolute ethanol (75 ml.) is added dropwise to a solution of ethyl-2-bromomethylacrylate (19.3 g.) in ethanol (25 ml.). After two hours, it is diluted with water (400 ml.) and extracted with methylene chloride. The organic layer is dried and concentrated to dryness in vacuo to yield ethyl-2-methylthiomethylacrylate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04228077 |
| Source dataset | uspto-grants-1980_10 |
| ORD ID | ord-3eb3db7c0d1448cd9ea72ab3aae6da10 |
| Source note | uspto-grants-1980_10 |