HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydroquinone → HCID 9990299, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydroquinone | HCID 785 | — |
| Reactant | Methyl Methacrylate | HCID 6658 | — |
| Reactant | Dibutylamine | HCID 8148 | — |
| Reactant | Dibutylammonium chloride | HCID 3083954 | — |
| Product | HCID 9990299 | HCID 9990299 | 15% |
Reaction Steps
200 g of methyl methacrylate, 129 g of dibutylamine, 8.25 g of dibutylamine hydrochloride, 5 g of Fe-(III)-acetylacetonate, and 0.5 g of hydroquinone were heated for 3 hours at 230° C. in an autoclave (pmax =10 atmospheres). In this way, a 15% yield of N,N-dibutylmethacrylic acid amide form. The selectivity, calculated on the methyl methacrylate reacted, was greater than 80%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04228102 |
| Source dataset | uspto-grants-1980_10 |
| ORD ID | ord-fc16420003204edf87b46a7db1756257 |
| Source note | uspto-grants-1980_10 |