HuagongsheHuagongshe Chemistry Print Report · For research reference only
Thionyl Chloride → 2-Methoxy-10,11-dihydrodibenzo[b,f]thiepin-9-carbonyl chloride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Thionyl Chloride | HCID 24386 | — |
| Reactant | Dibenzo(b,f)thiepin-1-carboxylic acid, 10,11-dihydro-8-methoxy- | HCID 3045903 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | 2-Methoxy-10,11-dihydrodibenzo[b,f]thiepin-9-carbonyl chloride | HCID 23337065 | — |
Reaction Steps
An amount of 572 mg of 2-methoxy-9-carboxy-10,11-dihydrodibenzo[b,f]thiepin was dissolved in 10 ml of anhydrous benzene and to the mixture was added 1 ml of thionyl chloride. The resulting mixture was refluxed for 3 hours and freed of solvent under reduced pressure to obtain 614 mg of 2-methoxy-10,11-dihydrodibenzo[b,f]thiepin-9-carbonyl chloride.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04228284 |
| Source dataset | uspto-grants-1980_10 |
| ORD ID | ord-25438a72e0dd449e88f4c81fd116d60e |
| Source note | uspto-grants-1980_10 |