Benzoyl Peroxide → HCID 22420136, compound

HRID 904274Notes

Reaction equation

HRID 904274 reaction equation
[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[CH:9]([CH:11]([Cl:18])[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)=[CH2:10].C(C1C=CC=CC=1C=C)=C.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>O>[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[CH:9]([CH:11]([Cl:18])[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)=[CH2:10]

Participants

6

Reactant 4

HCID 7187Benzoyl PeroxideHCID 7501StyreneHCID 666661,2-DiethenylbenzeneHCID 11768772Benzene, 1-(chloromethyl)-3(or 4)-ethenyl-

Product 1

HCID 22420136HCID 22420136, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Conditions

Temperature
80 °C

Procedure

Styrene 123 g (1.18 moles), vinylbenzyl chloride 14 g (0.090 moles), divinyl benzene 30 g (0.225 moles), benzoyl peroxide 0.75 g, and 1.0 ml of mineral oil were added to 45 ml of warm water (80° C.) containing 4.5 g of soluble starch and stirred at 400 rpm at 80° C. for 24 hours. The reaction mixture was cooled and the white spherical polymer was screened through a fine mesh sieve (#100) and washed with organic solvents and water, and then dried overnight at 80° C. The polymer contained about 1.88% of chlorine.

Workup

  1. temperatureThe reaction mixture was cooled
  2. washwashed with organic solvents and water
  3. customdried overnight at 80° C

Sources & evidence

ORD record
ord-7878da83200c4ee69f71eb9a81029088
Source dataset
uspto-grants-1980_10
Patent number
US04230828

Reaction notes

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