Ethanol → HCID 178522658, compound

HRID 904636Notes

Reaction equation

HRID 904636 reaction equation
[OH-:1].[Na+].[NH2:3][C:4]1[CH:17]=[CH:16][CH:15]=[CH:14][C:5]=1[C:6]([NH:8][C:9]1[NH:13][N:12]=[N:11][N:10]=1)=[O:7].C([OH:20])C>[Pd]>[N+:3]([C:4]1[CH:17]=[CH:16][CH:15]=[CH:14][C:5]=1[C:6]([NH:8][C:9]1[NH:13][N:12]=[N:11][N:10]=1)=[O:7])([O-:20])=[O:1]

Participants

5

Reactant 3

HCID 702EthanolHCID 14798Sodium HydroxideHCID 178507500HCID 178507500, compound

Product 1

HCID 178522658HCID 178522658, compound

Reagents, catalysts & solvents 1

HCID 23938PalladiumCatalyst

Procedure

Hydrogenation of 19 g of 2-nitro-N-(1H-tetrazol-5-yl)benzamide in 100 ml of aqueous 1N sodium hydroxide solution and 100 ml of ethanol using 0.5 g of 5% Pd/C catalyst and 2 atmospheres pressure gave 2-amino-N-(1H-tetrazol-5-yl)benzamide melting at about 253°-254° C.

Sources & evidence

ORD record
ord-5f6d7e5c67bd42cab3bb1407212964d0
Source dataset
uspto-grants-1983_12
Patent number
US04419357

Reaction notes

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