Trimethoxysilane → HCID 20476617, compound

Participants

Reaction Conditions

Reaction Steps

To a one-ounce glass vial containing 6.7 gms (0.026 moles) of 7-allyl-8-trimethylsiloxyquinoline was added 6.34 gms (0.052 moles) of trimethoxysilane and a trace of platinum catalyst (H2PtCl6 4H2O). Some bubbling occurred. The reaction was warmed at 40° C. for 8 hours during which time the reaction was monitored by GLC. A GLC after 3 days at 40° C. showed a small amount of the starting silane and a large product peak corresponding to ##STR17## Analysis showed nd25 =1.525. Infra-red analysis showed the disappearance of the C=C peak. H'NMR:

Provenance & Evidence