2,4,6-Trichlorophenol → HCID 20476806, compound

Participants

Reaction Steps

In a manner analogous to that described in Example 1, 17.5 g of triisobutylaluminum and 17.4 g of 2,4,6-trichlorophenol are reacted in absolute toluene to give (2,4,6-trichlorophenoxy)diisobutylaluminum and this is then reacted with 22.4 g of pyridine-N-oxide-2-thiol to afford the title compound. The isolation of the product is carried out in analogous manner. The yield of (2,4,6-trichlorophenoxy)bis(2-pyridinethiolato)-aluminum N,N'-dioxide, a fine white powder with a melting point of 207°-208° C., is 28.6 g, about 68% of theory.

Provenance & Evidence