1-methyl-1,3,5-triazine-2,4(1h,3h)-dione → 1-Butyl-1,3,5-triazinane-2,4-dione

HRID 905350Notes

Reaction equation

HRID 905350 reaction equation
[CH2:1]([N:5]1[CH:12]=[N:11][C:9](=[O:10])[NH:8][C:6]1=[O:7])[CH2:2][CH2:3][CH3:4].CN1C=NC(=O)NC1=O>>[CH2:1]([N:5]1[CH2:12][NH:11][C:9](=[O:10])[NH:8][C:6]1=[O:7])[CH2:2][CH2:3][CH3:4]

Participants

3

Reactant 2

HCID 2535131-methyl-1,3,5-triazine-2,4(1h,3h)-dioneHCID 20476324HCID 20476324, compound

Product 1

HCID 204763211-Butyl-1,3,5-triazinane-2,4-dioneYield 67%

Procedure

Following the procedure described in Preparation 2, Part C, above, but substituting the 1-n-butyl-5-azauracil prepared in Part B, above, for the 1-methyl-5-azauracil, there is prepared 40 gm. (67% yield) of the desired new precursor 5-n-butyl-5,6-dihydro-s-triazine-2,4-(1H,3H)-dione having a melting point of 205° C. to 207° C.

Workup

  1. customdescribed in Preparation 2, Part C
  2. customprepared in Part B

Sources & evidence

ORD record
ord-3059044b7c484ad3aa2441285e02d297
Source dataset
uspto-grants-1983_12
Patent number
US04423212

Reaction notes

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