Carbon Dioxide → HCID 131729134, compound

HRID 905508Notes

Reaction equation

HRID 905508 reaction equation
[C:1]([OH:7])(=[O:6])[CH2:2][C:3]([OH:5])=[O:4].C(=O)(O)O.[NH2:12][C:13]([NH2:15])=[NH:14].C(=O)=O>O>[C:1]([O-:7])(=[O:6])[CH2:2][C:3]([O-:5])=[O:4].[NH2:14][C:13]([NH2:15])=[NH2+:12].[NH2:14][C:13]([NH2:15])=[NH2+:12]

Participants

5

Reactant 3

HCID 280Carbon DioxideHCID 867Malonic AcidHCID 286947Carbonic acid-guanidine (1:1)

Product 1

HCID 131729134HCID 131729134, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Malonic acid (1.00 g, 9.61 mmol) was dissolved in 30 ml of distilled water. Guanidine carbonate (1.73 g, 9.61 mmol) was added via syringe at room temperature (carbon dioxide gas was evolved) and the reaction was stirred at room temperature for 24 hours. The water was removed in vacuo with heating to approximately 90° C. for 4 hours. The product was isolated as a white solid.

Workup

  1. customThe water was removed in vacuo
  2. temperaturewith heating to approximately 90° C. for 4 hours
  3. customThe product was isolated as a white solid

Sources & evidence

ORD record
ord-691bda8024df427ebdc4c7814c53ac21
Source dataset
uspto-grants-2011_09
Patent number
US08012277B2

Reaction notes

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