HuagongsheHuagongshe Chemistry Print Report · For research reference only
Cerium(III) chloride → HCID 59273084, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Cerium(III) chloride | HCID 24636 | — |
| Reactant | benzyl (2S)-2-isopropyl-3-oxopyrrolidine-1-carboxylate | HCID 59273063 | — |
| Reactant | HCID 178467822 | HCID 178467822 | — |
| Product | HCID 59273084 | HCID 59273084 | — |
Reaction Steps
By an operation in the same manner as in Reference Example 3 and using cerium chloride (6.35 g), 3 mol/L methylmagnesium bromide-diethyl ether solution (7.55 mL) and benzyl (2S)-2-isopropyl-3-oxopyrrolidine-1-carboxylate (2.7 g), the title compound was obtained as pale-yellow oil (yield: 1.78 g, yield: 62%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08013008B2 |
| Source dataset | uspto-grants-2011_09 |
| ORD ID | ord-79143bb39937466f90d6da6a58536a74 |
| Source note | uspto-grants-2011_09 |